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Презентация на тему Water and its properties

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LESSON OBJECTIVES:Water and its structureTo explore the unique properties of water as the cohesion, adhesion, capillary water and surface tensionChemical properties of water as solvent Water Hardness
LECTURE №8WATER AND ITS PROPERTIES28.03.2016 LESSON OBJECTIVES:Water and its structureTo explore the unique properties of water as Water is a transparent fluid which forms the world's streams, lakes, oceans Water is a buffer that regulates body temperature (through sweating and vasoconstriction)Water Water is a liquid at standard ambient temperature and pressure, but it WATER PHASES CHANGES As a chemical compound, a water molecule contains one oxygen and two Unevenly distributed charges due to unequal forces placed on bonding electrons:Oxygen ends As result of polarity water molecules form Hydrogen bonds:slightly positive chargeCharge hydrogen PHYSICAL PROPERTIES OF WATER:	Water has a high specific heat. Water in a pure COHESION  Water is attracted to water is a various intermolecular forces Surface Tension Is a property of the surface of a liquid that Capillary Action:	Capillary action is important for moving water (and all of the Density:Water has a density of 1g/mL at 4 °CWater is the one of Properties of WaterAt sea level, pure water boils at 100 °C and Water is Universal Solvent:Ions and polar molecules readily dissolve in water Substances A substance that can behave as either an acid or a base Pure water has a low electrical conductivity, but this increases significantly with CHEMICAL PROPERTIES OF WATER:pH (activity acidity)Total AcidityAlkalinityTotal HardnessChemical reactivity: water can participate REACTION OF WATER WITH METALSNot all metals react with water.Metals of Group 1 (IA or DISSOLVING ELECTROLYTES IN WATERSolid electrolytes are composed of ions which are held Is a chemical process in which a molecule is cleaved into two TOTAL HARDNESS	One important indicators of water quality is its hardness. General hardness These TYPES / CLASSIFICATION OF HARDNESSTemporary (carbonate) hardness:Ca(HCO3)2, Mg(HCO3)2Permanent (non-carbonate) hardness:CaCl2, CaSO4MgCl2, MgSO4GENERAL Temporary hardness is due to the presence of bi-carbonates of calcium and It is due to the presence of chlorides and sulphates of calcium Removal of Hardness Boiling Addition of lime Addition of sodium carbonates Base Measurement of Hardness	Expressed as millimole equivalents of Ca2+ and Mg2+ cations in 1 ESTIMATION OF WATER HARDNESS	Water hardness can be determined by the following 2 ESTIMATION OF TEMPORARY HARDNESS BY TITRATION WITH HCL:For determining temporary hardness: 100 Add 1ml of buffer solution (NH4OH+NH4Cl) to 100 ml of the original Eriochrome Black Indicator reacted with metal ions in water and changed its Permanent hardness can be found by deducting the temporary hardness from total CONCLUSION:	The safe drinking water is recognized water:with pH of 7 to 7.5 RULES OF USING A BURET:Clean the buret with a buret brush, water, Use a marker pen to create a black area on a white If you need to dispense less than a full drop of titrant, КИПЯЧЕНИЕ ВОДЫЖесткость снижается на 30 - 40%. ВЫМОРАЖИВАНИЕ ВОДЫОбщая жесткость снижается на 70-80%. ФИЛЬТРАЦИЯОбщая жесткость понижается на 80%. Что такое бытовой фильтр?Внутри картриджа фильтра содержится смесь из активированного угля (черные УМЯГЧИТЕЛИ ВОДЫ GLOSSARYAdhesion – the ability of a substance to stick to an unlike
Слайды презентации

Слайд 2 LESSON OBJECTIVES:

Water and its structure

To explore the unique

LESSON OBJECTIVES:Water and its structureTo explore the unique properties of water

properties of water as the cohesion, adhesion, capillary water

and surface tension

Chemical properties of water as solvent

Water Hardness

Слайд 3 Water is a transparent fluid which forms the

Water is a transparent fluid which forms the world's streams, lakes,

world's streams, lakes, oceans and rain, and is the

major constituent of the fluids of living things.




Слайд 4 Water is a buffer that regulates body temperature

Water is a buffer that regulates body temperature (through sweating and

(through sweating and vasoconstriction)
Water helps to hydrate the body:


Our cells are composed of roughly 75% water.

Our blood is composed of roughly 90% water.


Слайд 5 Water is a liquid at standard ambient temperature

Water is a liquid at standard ambient temperature and pressure, but

and pressure, but it often co-exists on Earth with

its solid state, ice; and gaseous state, steam (water vapor). It also exists as snow, fog, dew and cloud.


snow

fog

dew

clouds


Слайд 6 WATER PHASES CHANGES

WATER PHASES CHANGES

Слайд 7 As a chemical compound, a water molecule contains

As a chemical compound, a water molecule contains one oxygen and

one oxygen and two hydrogen atoms that are connected

by ................ bonds.

Water is:
Composed of two hydrogen atoms and one oxygen atoms
H2O
Polar Molecule has oppositely charged ends

covalent


Слайд 8 Unevenly distributed charges due to unequal forces placed

Unevenly distributed charges due to unequal forces placed on bonding electrons:Oxygen

on bonding electrons:
Oxygen ends slightly negative
Hydrogen end slightly positive
Water

molecule is a polar and a dipole

Слайд 9 As result of polarity water molecules form Hydrogen

As result of polarity water molecules form Hydrogen bonds:slightly positive chargeCharge

bonds:
slightly positive
charge
Charge hydrogen bond between (+) and (-)

areas of different water molecules

slightly negative
charge


Слайд 10 PHYSICAL PROPERTIES OF WATER:

Water has a high specific heat.

PHYSICAL PROPERTIES OF WATER:	Water has a high specific heat. Water in a


Water in a pure state has a neutral pH. As

a result, pure water is neither acidic nor basic. Water changes its pH when substances are dissolved in it.
Water conducts heat more easily than any liquid except mercury.
Water molecules exist in liquid form over an important range of temperature from 0 - 100° Celsius.
Water has a high surface tension.
Water is a universal solvent.

Слайд 11 COHESION
Water is attracted to water
is

COHESION Water is attracted to water is a various intermolecular forces

a various intermolecular forces that hold solids and liquids

together
hydrogen bonding locks molecules together.

ADHESION
Water is attracted to other substances
Water is adhesive to any substance with which it can form hydrogen bonds.

Thus the forces between molecules in a drop of water are cohesive, while the mutual attraction between water and glass represents adhesion.


Слайд 13 Surface Tension
Is a property of the surface

Surface Tension Is a property of the surface of a liquid

of a liquid that allows it to resist an

external force, due to the cohesive nature of the water molecules.
Water molecules want to cling to each other. At the surface, however, there are fewer water molecules to cling to since there is air above (thus, no water molecules). This results in a stronger hydrogen bond between those molecules that actually do come in contact with one another, and a layer of strongly bonded water (see diagram). This surface layer (held together by surface tension) creates a considerable barrier between the atmosphere and the water.

Surface tension allows insects to float and stride on a water surface.


Слайд 14 Capillary Action:
Capillary action is important for moving water

Capillary Action:	Capillary action is important for moving water (and all of

(and all of the things that are dissolved in

it) around. It is defined as the movement of water within the spaces of a porous material due to the forces of adhesion, cohesion, and surface tension.


meniscus


Слайд 15 Density:
Water has a density of 1g/mL at 4 °C
Water

Density:Water has a density of 1g/mL at 4 °CWater is the one

is the one of the few substances that is

less dense as a solid than liquid
Due to hydrogen bonding and resultant pockets

ice floats on water because
it is less dense


Слайд 16
Properties of Water
At sea level, pure water boils

Properties of WaterAt sea level, pure water boils at 100 °C

at 100 °C and freezes at 0 °C.

The

boiling temperature of water decreases at higher elevations (lower atmospheric pressure).

For this reason, an egg will take longer to boil at higher altitudes

Слайд 17 Water is Universal Solvent:
Ions and polar molecules readily

Water is Universal Solvent:Ions and polar molecules readily dissolve in water

dissolve in water
Substances such as salt are pulled

apart by attraction of opposite charges due to polar structures

Слайд 18 A substance that can behave as either an

A substance that can behave as either an acid or a

acid or a base is called, amphoteric (ampholyte):
acid
base
ampholyte
All the

major components in cells (proteins, DNA and polysaccharides) are also dissolved in water.

Слайд 19 Pure water has a low electrical conductivity, but

Pure water has a low electrical conductivity, but this increases significantly

this increases significantly with the dissolution of a small

amount of ionic material such as sodium chloride.

Слайд 20 CHEMICAL PROPERTIES OF WATER:

pH (activity acidity)
Total Acidity
Alkalinity
Total Hardness
Chemical

CHEMICAL PROPERTIES OF WATER:pH (activity acidity)Total AcidityAlkalinityTotal HardnessChemical reactivity: water can

reactivity: water can participate in chemical reactions. Example: involvement

of water molecules in dehydration synthesis and hydrolysis, electrolysis.
Metals – Iron, Manganese, Zinc, Copper, Chromium, Lead
Nitrate/ Nitrite
Arsenic, Selenium, Fluoride
Chloride
Total and Free Chlorine
In practice, the chemical properties of water are determined by analytical methods.

Слайд 21 REACTION OF WATER WITH METALS

Not all metals react with water.
Metals

REACTION OF WATER WITH METALSNot all metals react with water.Metals of Group 1 (IA

of Group 1 (IA or alkali) react vigorously with cold

water forming hydroxide and hydrogen gas:


Metals from magnesium to iron in the activity series of metals, react with steam (but not H2O) to form the metal oxide and hydrogen gas:



Noble metals, such as gold and silver, do not react with water at all.

Слайд 22 DISSOLVING ELECTROLYTES IN WATER
Solid electrolytes are composed of

DISSOLVING ELECTROLYTES IN WATERSolid electrolytes are composed of ions which are

ions which are held together by electrostatic forces of

attraction. When an electrolyte is dissolved in water, these forces are weakened and the electrolyte undergoes dissociation into ions. The ions are solvated.

acid: HCl (g) + H2O (aq) = H+ (aq) + Cl-(aq)

base: NaOH (s) + H2O (aq) = Na+ (aq) + OH-(aq)

salt: NaCl(s) + H2O (aq) = Na+ (aq) + Cl-(aq)

The process of splitting of the molecules into ions of an electrolyte is called dissociation .


Слайд 23 Is a chemical process in which a molecule

Is a chemical process in which a molecule is cleaved into

is cleaved into two parts by the addition of

a molecule of water ("chemical decomposition by water," 1880, formed in English from hydro- + Greek lysis "a loosening, a dissolution," from lyein "to loosen, dissolve").

AB + H-OH ⇌ A-H + B-OH

HYDROLYSIS


Слайд 24 TOTAL HARDNESS

One important indicators of water quality is

TOTAL HARDNESS	One important indicators of water quality is its hardness. General

its hardness. General hardness (GH) is caused by the

presence of a certain concentration of calcium (Са2+) and magnesium (Mg2+) ions in 1 liter of water:

Слайд 25 These "hardness ions" cause two major kinds of

These

problems. First, the metal cations react with soaps, causing

them to form an unsightly precipitate – the familiar "bathtub ring".
More seriously, the calcium and magnesium carbonates tend to precipitate out as adherent solids on the surfaces of pipes and especially on the hot heat exchanger surfaces of boilers. The resulting scale buildup can impede water flow in pipes.

In boilers, the deposits act as thermal insulation that impedes the flow of heat into the water; this not only reduces heating efficiency, but allows the metal to overheat, which in pressurized systems can lead to catastrophic failure.


Слайд 26 TYPES / CLASSIFICATION OF HARDNESS
Temporary (carbonate) hardness:
Ca(HCO3)2,
Mg(HCO3)2
Permanent

TYPES / CLASSIFICATION OF HARDNESSTemporary (carbonate) hardness:Ca(HCO3)2, Mg(HCO3)2Permanent (non-carbonate) hardness:CaCl2, CaSO4MgCl2,


(non-carbonate) hardness:
CaCl2, CaSO4
MgCl2, MgSO4
GENERAL HARDNESS:
GH = TH + PH


Слайд 27 Temporary hardness is due to the presence of

Temporary hardness is due to the presence of bi-carbonates of calcium

bi-carbonates of calcium and magnesium. It can be removed

by easy means like boiling. When temporary hard water is boiled, the carbonates decompose with liberation of carbon-dioxide and precipitation of the insoluble Carbonates which are reformed:



MgCO3 is slightly soluble in water but heating will cause its hydrolysis into the much less soluble Mg(OH)2


So simple boiling and filtering of water remove temporary hardness.



TEMPORARY HARDNESS


Слайд 28 It is due to the presence of chlorides

It is due to the presence of chlorides and sulphates of

and sulphates of calcium and magnesium. These salts do

not decompose on boiling. So permanent hardness can’t be removed easily. It can be removed by soda (Na2CO3), surfactants (Na3PO4) or lime (Ca(OH)2) when MgSO4 is responsible for hardness:

PERMANENT HARDNESS

Surfactant a substance that tends to reduce the surface tension of a liquid in which it is dissolved.


Слайд 29 Removal of Hardness
Boiling
Addition of lime

Removal of Hardness Boiling Addition of lime Addition of sodium carbonates


Addition of sodium carbonates
Base exchange process



Addition of Sodium carbonate
Base exchange process:
Sodium Permutit is used ( Na2Al2 Si2O H2O )
Exchange Na ions for Ca and Mg ions
Ca and Mg Permutit is formed .
Removes 100% hardness
Some raw water is added to protect against corrosive action of 100% soft water



Temporary Hardness

Permanent Hardness


Слайд 30 Measurement of Hardness
Expressed as millimole equivalents of Ca2+ and

Measurement of Hardness	Expressed as millimole equivalents of Ca2+ and Mg2+ cations in

Mg2+ cations in 1 liter of the water (mmole-Eq/L).
On

scale hardness distinguishes:



Слайд 31 ESTIMATION OF WATER HARDNESS

Water hardness can be determined

ESTIMATION OF WATER HARDNESS	Water hardness can be determined by the following

by the following 2 analytical methods:
By titration with HCl:

In this method temporary hardness can be measured.
By titration with EDTA: In this method general hardness can be measured.

Слайд 32

ESTIMATION OF TEMPORARY HARDNESS BY TITRATION WITH HCL:
For

ESTIMATION OF TEMPORARY HARDNESS BY TITRATION WITH HCL:For determining temporary hardness:

determining temporary hardness: 100 ml hard water is taken

into a 250 ml conical flask. Then few 3-4 drops of methyl orange is added in it as an indicator. Now titration is carried out by adding 0.1N cold HCl until the yellow color of methyl orange turns red.
Here, each meal 0.1N HCl is equivalent to 0.005 gm of CaCO3. The associated reactions are as follows:




Слайд 33 Add 1ml of buffer solution (NH4OH+NH4Cl) to 100

Add 1ml of buffer solution (NH4OH+NH4Cl) to 100 ml of the

ml of the original water sample. Add 3-4 drops

of Eriochrome Black T indicator. Titrate against 0.05N prepared EDTA solutions in burette until the color charges from wine red (or violet) to pure blue (or turquoise) with no reddish tone; then calculate the general hardness:

ESTIMATION OF GENERAL HARDNESS BY TITRATION WITH EDTA:


Слайд 34 Eriochrome Black Indicator reacted with metal ions in

Eriochrome Black Indicator reacted with metal ions in water and changed

water and changed its color:

Lab # 3 Water Hardness


Слайд 35

Permanent hardness can be found by deducting the

Permanent hardness can be found by deducting the temporary hardness from

temporary hardness from total hardness i.e.
Permanent = General hardness

– Temporary
hardness hardness

GH = TH + RH



Слайд 36 CONCLUSION:

The safe drinking water is recognized water:
with pH

CONCLUSION:	The safe drinking water is recognized water:with pH of 7 to

of 7 to 7.5 mmol / L
hardness not

more than 7 mmol / L,
the total amount of minerals in which not more than 1 g / l,
harmful chemical impurities do not exceed the maximum allowable concentrations,
and lacking pathogenic bacteria and viruses.

Слайд 38 RULES OF USING A BURET:
Clean the buret with

RULES OF USING A BURET:Clean the buret with a buret brush,

a buret brush, water, and a small amount of

detergent. Rinse it twice with deionized water. Be sure to drain deionized water through the tip.
Rinse the buret again with two 10 mL portions of the titrant (HCl or EDTA solutions)
Fill the buret with titrant and drain a small amount from the buret to dispel any air bubbles that might be in the tip.

Слайд 39 Use a marker pen to create a black

Use a marker pen to create a black area on a

area on a white note card. This will be

used to help locate the bottom of the meniscus when reading the buret.


Place the note card with the black mark behind the buret and just below the meniscus. This will make the bottom of the meniscus much easier to see. Record the volume reading to the nearest 0.01 mL.

Слайд 40 If you need to dispense less than a

If you need to dispense less than a full drop of

full drop of titrant, open the stopcock slightly to

allow a small amount of titrant to accumulate on the tip of the buret.


Rinse the titrant on the tip into the flask using deionized water from your wash bottle.


Слайд 41 КИПЯЧЕНИЕ ВОДЫ
Жесткость снижается на 30 - 40%.

КИПЯЧЕНИЕ ВОДЫЖесткость снижается на 30 - 40%.

Слайд 42 ВЫМОРАЖИВАНИЕ ВОДЫ
Общая жесткость снижается на 70-80%.

ВЫМОРАЖИВАНИЕ ВОДЫОбщая жесткость снижается на 70-80%.

Слайд 43 ФИЛЬТРАЦИЯ
Общая жесткость понижается на 80%.

ФИЛЬТРАЦИЯОбщая жесткость понижается на 80%.

Слайд 45 Что такое бытовой фильтр?
Внутри картриджа фильтра содержится смесь

Что такое бытовой фильтр?Внутри картриджа фильтра содержится смесь из активированного угля

из активированного угля (черные частицы) и катионообменники (гранулы смолы

белого цвета).
Уголь адсорбирует вредные органические вещества и хлориды.
Катионообменники снижают общую жесткость.

Слайд 46 УМЯГЧИТЕЛИ ВОДЫ

УМЯГЧИТЕЛИ ВОДЫ

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